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filingDate 2021-04-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2022-05-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2022-05-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-113214493-B
titleOfInvention Preparation of cobalt-based metal organic framework material and low-carbon hydrocarbon separation application thereof
abstract A preparation method of a cobalt-based metal organic framework material and a low-carbon hydrocarbon separation application thereof belong to the technical field of crystalline porous material preparation and gas separation. The MOF material is prepared from organic ligand 5,5 '-bis (1H-pyrazol-4-yl) -2,2' -Dipyridine (DPBP) and cobalt acetate (Co (CH) 3 COO) 2 ) Synthesized under solvothermal conditions. The Co-DPBP has a regular pore channel structure, high porosity and specific surface area. The size of the pore canal is slightly larger than the kinetic diameter of the propine/propylene molecule, and the pore canal contains abundant naked metal sites and hydrogen bond action sites. The acting force between the Co-DPBP framework and the propyne molecules is stronger, so that the effect of preferentially adsorbing the propyne in the propyne-propylene mixed gas is realized, and the propylene component in the mixed gas is purified.
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Total number of triples: 44.