http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-113045778-B
Outgoing Links
Predicate | Object |
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classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08J2351-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08J2333-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08J2451-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08J2433-08 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08J3-075 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F8-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F220-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F283-065 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08J3-246 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08L51-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F220-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F283-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F220-54 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08J3-075 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F220-34 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08L33-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08J3-24 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F8-12 |
filingDate | 2021-03-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2022-05-31-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2022-05-31-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-113045778-B |
titleOfInvention | Preparation method of dual-response self-repairing hydrogel |
abstract | The invention belongs to the technical field of high polymer materials, and relates to a dual-response self-repairing hydrogel and a preparation method thereof. P-nitrobenzaldehyde is reduced to obtain P-aminobenzaldehyde, the P-aminobenzaldehyde is subjected to diazo coupling reaction to prepare 4- ((4-hydroxyphenyl) diazenyl) benzaldehyde), then, 4- ((4-formylphenyl) diazenyl) phenyl methacrylate is prepared through acylation reaction, and the phenyl benzaldehyde and polyethylene glycol methyl ether methacrylate are subjected to free radical copolymerization to prepare the water-soluble gel factor P (Azo-co-EGMA) containing azobenzene and aldehyde group. Copolymerizing N-isopropylacrylamide and methyl acrylate to obtain poly (N-isopropylacrylamide-co-methyl acrylate), and hydrolyzing the poly (N-isopropylacrylamide-co-acrylhydrazide) in hydrazine hydrate to obtain poly (N-isopropylacrylamide-co-acrylhydrazide) serving as a second gel factor. And (3) forming reversible acylhydrazone bonds by the two gel factors through hydrazide groups and aldehyde groups to form the dual-response self-repairing hydrogel through crosslinking. |
priorityDate | 2021-03-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 76.