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filingDate 2021-01-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3658a53f2eb97a58f15da8df3f5bacb9
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publicationDate 2021-06-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-112946035-A
titleOfInvention A long-acting reference electrode for steel corrosion monitoring and preparation method thereof
abstract The invention belongs to the technical field of electrochemical sensors, and particularly relates to a long-acting reference electrode for steel corrosion monitoring and a preparation method thereof. The preparation method of the present invention comprises the following steps: (1) depositing manganese dioxide on the metal foam, and then partially reducing the manganese dioxide to MnOOH to obtain a metal foam loaded with MnO 2 /MnOOH; (2) polymerizing dopamine on the metal foam by auto-oxidation Polydopamine is generated on the surface of the metal foam loaded with MnO 2 /MnOOH, and the polydopamine is carbonized to obtain a MnO 2 /MnOOH/carbon nanoparticle composite electrode; (3) The composite electrode is drawn out of the wire, and the electrode is packaged to obtain a long-lasting reference electrode. . The invention can uniformly and tightly load manganese active material on the current collector foam nickel, the conductive carbonized polydopamine skeleton avoids the use of non-conductive binder, reduces the contact resistance, and exhibits good electrochemical reversibility and anti-polarity It can serve with high stability in long-term monitoring of steel corrosion state and chloride ion penetration rate.
priorityDate 2021-01-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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