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filingDate 2021-01-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2022-08-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2022-08-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-112938935-B
titleOfInvention A kind of porous carbon nanosphere supported carbon-coated cobalt phosphide material and its preparation method and application
abstract The invention relates to a porous carbon nanosphere-supported carbon-coated cobalt phosphide material, a preparation method and application thereof, and belongs to the technical field of electrocatalysts. Using core-shell structured Co-MOF@Zn-MOF as precursor, phosphorus-doped Co-MOF was prepared by introducing phosphorus into Co-MOF@Zn-MOF by selective phosphorylation of ammonium phosphate and zinc ions @Zn‑MOF, after carbonization. Compared with the cobalt phosphide prepared by the traditional phosphating technology, this technology of phosphorylating the precursor in advance improves the disadvantage of the toxic PH emission in the traditional NaH 2 PO 2 phosphating technology. At the same time, due to the carbon-coated structure, The nano-cobalt phosphide is uniformly distributed on the porous carbon spheres. The electrode modified with this material has high sensing sensitivity and low detection limit for dopamine, and can be used for the detection of dopamine in human serum.
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