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filingDate 2019-12-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2022-04-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2022-04-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-112892603-B
titleOfInvention Solid heterogeneous catalyst for nitrogen formylation reaction and preparation and application thereof
abstract The invention relates to a solid heterogeneous catalyst and a preparation method and application thereof, and more particularly relates to a solid heterogeneous catalyst applied to nitrogen formylation reaction, which consists of a metal component and an organic ligand polymer, wherein the organic ligand polymer is a polymer which is generated by carrying out solvent thermal polymerization on a phosphine ligand monomer containing vinyl functional groups and has a large specific surface area and a hierarchical pore structure, forms coordinate bonds, and is highly dispersed and stably present on an organic ligand polymer carrier. In the nitrogen formylation reaction of the catalyst, on one hand, the metal component and the P atom in the polymer carrier exist on the carrier stably due to the coordination; on the other hand, the polymer carrier has large specific surface area and a hierarchical pore structure, and the metal components can be highly dispersed on the carrier, so that the solid heterogeneous catalyst has excellent catalytic reaction performance and stability, is easy to separate from reactants and products, and has wide industrial application prospects.
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