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filingDate 2021-01-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2022-06-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2022-06-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-112768652-B
titleOfInvention Sodium-manganese-phosphor-ore/carbon composite positive electrode material NaMnPO4Preparation method of/C
abstract The invention relates to a birnessite/carbon composite positive electrode material NaMnPO 4 The composite anode material has stable thermodynamic property, sodium ion electrochemical storage activity, good electronic conductivity, smaller ion diffusion impedance and extremely strong application value. The NaMnPO 4 The preparation process of the/C composite positive electrode material mainly comprises the following steps: preparing a manganese-based metal organic framework material precursor by taking metal manganese salt and an organic ligand as raw materials through a solvothermal method; then placing the mixture in an inert atmosphere for high-temperature heat treatment to obtain a MnO/C composite intermediate; ball milling and mixing the carbon composite intermediate and a proper amount of sodium dihydrogen phosphate; finally, tabletting the mixed powder and then carrying out Ar/H 2 Annealing at high temperature in atmosphere to finally prepare the birnessite/carbon composite anode material NaMnPO 4 and/C. The method is novel and effective, the raw material source is rich, the reaction equipment is simple, and the product is environment-friendly and nontoxic.
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