http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-112675920-B
Outgoing Links
Predicate | Object |
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classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D213-65 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D213-64 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D213-61 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F15-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D401-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-24 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D213-30 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-18 |
filingDate | 2020-12-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2022-12-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2022-12-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-112675920-B |
titleOfInvention | A class of monochiral center catalysts and methods for preparing and catalytically synthesizing chiral alcohol compounds and chiral α-allyl alcohols |
abstract | The invention relates to a class of single-chiral center catalysts and methods for preparing and catalytically synthesizing chiral alcohol compounds and chiral α-allyl alcohol. The above-mentioned monochiral center catalyst has a structure shown in the following general formula: In the formula, Z is -S-, -N=CH- or -CH=CH-. The above-mentioned catalyst uses achiral diphosphorus ligands while retaining and adjusting the chiral elements of the diamine ligands so that it can individually control the chirality of the catalytic asymmetric reaction, which greatly reduces the difficulty and cost of chiral catalyst synthesis, and the The catalyst can be used to catalyze the asymmetric transfer hydrogenation of aryl-aryl substituted, heterocyclic aromatic-aryl substituted, heterocyclic aryl-heterocyclic aryl substituted ketones, prepare chiral secondary alcohol compounds and realize elimination Kinetic resolution of α-allyl alcohols. |
priorityDate | 2020-12-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 90.