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filingDate 2020-11-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2022-07-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2022-07-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-112592484-B
titleOfInvention Preparation method and application of MOF materials constructed with 5-mercapto-1-phenyl-1H-tetrazolium as ligand and derivatives thereof
abstract The invention discloses a preparation method and application of a MOF material constructed by using 5-mercapto-1-phenyl-1H-tetrazolium as a ligand and a derivative thereof. The MOF material is prepared by dissolving a metal salt reagent in deionized water to obtain Solution A, 5-mercapto-1-phenyl-1H-tetrazolium ligand is dissolved in an organic solvent to obtain a white solution B, after the two solutions are mixed with ultrasonic, heated and reacted, the supernatant is removed by centrifugation, and the precipitate is removed by centrifugation. After washing to neutrality, drying is performed to obtain the MOF material; the MOF material is heated and kept warm, and finally the derivative of the MOF material is obtained. The invention prepares a brand-new metal-organic framework material. The nitrogen-containing porous derivative carbon-based sulfide material can be obtained through high temperature calcination without adding a sulfur source. The derivative material can be applied to electrocatalytic oxygen evolution reaction and has very excellent performance. At the same time, the preparation method of the present invention is simple and convenient, with low cost and strong repeatability.
priorityDate 2020-11-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 53.