http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-112537802-A

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filingDate 2020-12-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_30e425c460e8bd41d2a3bc8e28bd25c5
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publicationDate 2021-03-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-112537802-A
titleOfInvention A kind of preparation method of high voltage lithium battery precursor doped with cobalt hydroxide
abstract The invention relates to the technical field of preparation of lithium battery precursors, in particular to a preparation method of high-voltage lithium battery precursors doped with cobalt hydroxide. In the early stage of the reaction of the present invention, a large number of cobalt hydroxide crystal nuclei are formed at a relatively high pH value (11.5-12.5), and then at a suitable temperature (40-60° C.) and pH value (10.0-11.0), doping element ions, Co-precipitation reaction occurs between cobalt ions and sodium hydroxide to obtain a single-phase doped cobalt hydroxide solid solution Co 1-x M x (OH) 2 ; the solid solution of the reaction system is controlled by adding ammonia water as a complexing agent and sedimenting the supernatant. content, so that the nuclei grow slowly, and finally form dense and uniform large-sized spherical particles. The prepared doped precursor is prepared into lithium cobalt oxide with high specific capacity and excellent cycle performance at voltages above 4.5V.
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