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publicationDate 2021-03-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-112537798-A
titleOfInvention A kind of preparation method of zinc cobaltate nanowire
abstract The invention provides a method for preparing zinc cobaltate nanowires. Cobalt chloride hexahydrate, zinc chloride and nitrotriacetic acid are added to deionized water, and magnetic stirring is performed until they are completely dissolved; then isopropanol is added to form a mixed solution, The mixed solution is transferred to a polytetrafluoroethylene reactor for hydrothermal reaction, and after the reaction is completed, it is cooled to room temperature, and the zinc cobaltate precursor product is obtained by washing with water and ethanol, centrifuging, and then drying in a vacuum drying box; The resulting zinc cobalt oxide product is heated in a muffle furnace to obtain mesoporous zinc cobalt oxide nanowires. The preparation method provided by the invention is rich in raw material resources, low in price, stable in production, high in yield, environmentally friendly and convenient for industrial production. The as-prepared zinc cobaltate nanowires have a porous hollow structure, which can effectively accommodate volume expansion and shorten the transfer distance of Li + and electrolyte, and can also accommodate huge volume changes during Li + insertion/extraction.
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