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filingDate 2020-10-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-09-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-09-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-112480345-B
titleOfInvention Metal salt @ ammonia aldehyde polymer nanosphere, preparation method and application
abstract The invention discloses metal salt @ ammonia-aldehyde polymer nanospheres, a preparation method and application. The invention uses amino-containing monomer and aldehyde-containing monomer to condense and polymerize into polymer ball under the catalysis of phosphorous acid, then adds aniline into the system, and etches the polymer ball into hollow ball through the competition reaction between the primary amine group contained in aniline in solution and the dynamic imine bond in the polymer ball; and then, after the polymer hollow sphere is placed in a metal salt solution with a certain concentration, the metal salt permeates into the cavity through the pore canal on the sphere wall by utilizing the difference of the internal concentration and the external concentration of the hollow sphere and is crystallized inside, so that the metal salt @ amino aldehyde polymer nanosphere is obtained. In the case of encapsulating easily migrating metal cations (e.g. Li) + ) And then, the pore passage on the outer spherical shell of the polymer is beneficial to the migration of ions, so that higher ionic conductivity is obtained, and the material has better application prospect as a solid electrolyte.
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