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publicationDate 2021-02-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-112378899-A
titleOfInvention Method for determining gold in crude lead sample by low-temperature separation ICP-AES (inductively coupled plasma-atomic emission Spectrometry) method
abstract A method for determining gold in a crude lead sample by a low-temperature separation ICP-AES method comprises the steps of dissolving the crude lead sample completely by dilute nitric acid, adding hydrochloric acid to precipitate lead, and boiling at low temperature for 5-15min to completely dissolve gold. Evaporating to remove acid to a small volume in the presence of a protective agent, cooling a sample to 0 ℃ by using an ice water mixture or a constant-temperature refrigerator, adding 60-80mL of absolute ethyl alcohol, further reducing the solubility of lead chloride, filtering and separating after 2 hours, evaporating and removing the ethyl alcohol in the filtrate, adding the protective agent again, slightly boiling to evaporate to a small volume, and carrying out constant volume determination. The method simply and skillfully separates the lead from the gold by precipitating the lead through the low-temperature ethanol. Experiments show that the solubility of lead chloride in 60-80% of glacial ethanol is only 0.1g, and the method utilizes the characteristics that the solubility of lead chloride in the glacial ethanol is reduced and the lead chloride is insoluble in ethanol, so that lead precipitate is separated from gold.
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