http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-112301375-B

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filingDate 2020-10-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2022-11-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2022-11-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-112301375-B
titleOfInvention A sulfur-modified Cu-based MOF material, preparation method and its application in electrocatalytic CO2 reduction reaction
abstract The invention relates to a sulfur-modified Cu-based MOF material, a preparation method and its application in electrocatalytic CO2 reduction reaction. The material is composed of sulfur and a Cu-based MOF, wherein the Cu-based MOF material is HKUST-1, and the Cu-based MOF material has a regular octahedral structure with a size of 10-100 microns. The material is prepared by preparing a Cu-based MOF precursor, preparing a sulfur-containing precursor solution, and adopting a wet chemical reaction method to dope sulfur into the Cu-based MOF material. When applied to the electrocatalytic CO 2 reduction reaction system, compared with the existing Cu-based materials, the present invention only needs a trace amount of sulfur to modify the Cu-based MOF material to significantly improve the selectivity of the electrocatalytic CO 2 reduction reaction to generate ethylene. Moreover, the method has the advantages of simple synthesis, low cost, short reaction period and high repeatability, and has a very important application in the field of clean energy.
priorityDate 2020-10-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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