http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-112194687-B
Outgoing Links
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classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-004 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D213-79 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D213-803 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C01B32-40 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-2217 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F15-045 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01D53-8671 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D213-803 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D213-79 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C01B32-40 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01D53-62 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01D53-86 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F15-04 |
filingDate | 2020-11-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2023-02-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2023-02-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-112194687-B |
titleOfInvention | A metal nickel complex with ether bond bridged bispyridine carboxylic acid as a ligand, its synthesis method and photocatalytic application |
abstract | The invention relates to the technical field of metal-organic complex photofunctional materials, and discloses a metal-nickel complex with ether bond bridged bispyridine carboxylic acid as a ligand, a synthesis method and an application thereof. The molecular formula of the metal nickel complex with ether bond bridged bispyridine carboxylic acid as the ligand is C 12 H 10 N 2 NiO 7 2(H 2 O), and its synthesis method is as follows: 2-fluoropyridine-6 ‑Formic acid and nickel chloride hexahydrate (NiCl 2 6H 2 O) are converted into ether bond ligands by dimolecular ligand 2‑fluoropyridine‑6‑formic acid under solvothermal conditions, and then coordinate with nickel to obtain dark blue colored blocky crystals. The synthesis method of the metal nickel complex with ether bond bridging type bispyridine carboxylic acid as the ligand is innovative, the structure is novel, and it has a certain photocatalytic effect. It can be used as a cheap photocatalyst to catalyze the reduction of carbon dioxide to carbon monoxide. . The operation method of the invention is simple, and has potential application value in photocatalytic reduction of carbon dioxide. |
priorityDate | 2020-11-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 47.