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filingDate 2019-07-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2021-01-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-112191275-A
titleOfInvention A fiber-chelated TiO2 visible light catalyst based on LMCT effect and N-doping and its preparation method
abstract The invention relates to a fiber chelating TiO2 visible light catalyst based on LMCT effect and N doping and a preparation method thereof, and is characterized in that: modified polyacrylonitrile fiber containing amidoxime chelating group and nanometer TiO2 crystal sol Through the coordination bonding, the TiO 2 catalyst containing anatase crystal form and N-doping is obtained. The preparation method is as follows: selecting butyl titanate as a titanium source, acetic acid and absolute ethanol as a hydrolysis inhibitor to prepare a sol containing nano-TiO 2 crystals, and then reacting it with amidoxime-modified polyacrylonitrile fibers to obtain a LMCT effect and N-doped fiber-chelated TiO visible photocatalysts. The method has the advantages of simple equipment, simple process and easy operation, and compared with the prior art, the catalyst of the present invention can realize visible light catalysis through LMCT and N-doping dual pathways, so it shows higher performance in the oxidative degradation of organic pollutants. photocatalytic activity.
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