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filingDate 2020-09-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-05-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-05-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-112186161-B
titleOfInvention Semi-filled one-dimensional nano longitudinal hole composite fiber membrane flexible electrode material and preparation method thereof
abstract The invention belongs to the technical field of electrode material preparation, and particularly relates to a semi-filled one-dimensional nano longitudinal hole composite fiber membrane flexible electrode material and a preparation method thereof. Synthesis of Sb by hydrothermal method 2 S 3 Or Bi 2 S 3 Nanorod, and then Sb is subjected to electrostatic spinning 2 S 3 Nanorod or Bi 2 S 3 Spinning the uniform mixture of the nanorods and the PAN spinning solution, and finally firing the electrostatic spinning product to respectively obtain the antimony carbon or bismuth carbon composite nanofiber membrane flexible electrode material with semi-filled one-dimensional nano longitudinal holes. The composite structure of the invention fully exerts the characteristics of high specific capacity of the metal antimony/bismuth and the characteristics of stable structure, good flexibility and high conductivity of the carbon material formed by PAN high-temperature treatment, and in addition, the volume expansion effect of the metal antimony/bismuth in the circulation process can be buffered by the semi-filling type longitudinal hole structure formed by partial volatilization of the antimony/bismuth.
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