http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-112142990-A

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filingDate 2020-09-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_92631f3ebd8e74d61dd65a3fea6628f1
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publicationDate 2020-12-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-112142990-A
titleOfInvention A new type of Ag coordination polymer crystal material and its preparation method and application
abstract The invention belongs to the technical field of optical materials, and in particular relates to a novel Ag coordination polymer crystal material Ag( μ -aca)( μ4 - bztpy) 1/2 , whose chemical formula is C 28 H 18 AgN 2 O 2 , and each The smallest asymmetric unit contains a crystallographically independent Ag + , half a bztpy ligand and an aca - counter anion; the crystal material of the present invention emits strong green light under ultraviolet light irradiation, and combined with fluorescence properties, it can be used as a sensor to detect Identify toxic organic small molecule nitrobenzene and polluting ions Fe 3+ , Cr 2 O 7 2‑ . The preparation method includes: mixing and stirring the ammonia solution of Ag 2 O, the ethanol solution of 1, 2, 4, 5-tetrakis(4-pyridyl) benzene and the ethanol solution of 9-anthracenecarboxylic acid, and crystallization after the reaction. . The preparation method of the invention has the advantages of simple operation, high yield, cost saving and favorable industrial production.
priorityDate 2020-09-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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