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filingDate 2020-09-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2020-12-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-112090454-A
titleOfInvention A kind of macroporous weakly basic styrene anion exchange resin method and its equipment
abstract The invention relates to a method for macroporous weakly basic styrene anion exchange resin, which comprises the following steps: in step 1, a mixed alcohol of butanol and dodecanol is used as a pore-forming agent, benzoyl peroxide is used as an initiator, gelatin and a small amount of Ammonium salt is used as a dispersant to cross-link and copolymerize styrene and divinylbenzene to obtain a copolymer of styrene-divinylbenzene; step 2, under the catalysis of zinc chloride, chloromethyl ether is used to perform chloromethylation on the white spheres. to obtain a chloromethylated copolymer; in the third step, the chlorine spheres are ammoniated with a dimethylamine solution to obtain a macroporous weakly basic anion exchange resin. Compared with the prior art, the anion exchange resin prepared by the present invention has The specific surface area can reach more than 65m2/g, the proportion of mesopores larger than 2nm is more than 55%, the total exchange capacity can reach 4.6mmol/g, and the weak base exchange capacity can reach more than 3.6mmol/g.
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