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filingDate 2020-09-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6368d976fd97be0585c196d2674c1079
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publicationDate 2020-11-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-111996004-A
titleOfInvention Preparation method and application of rare earth doped potassium fluoride bismuth potassium luminescent nanomaterial
abstract The present disclosure belongs to the field of rare earth doped luminescent materials, and specifically provides a preparation method and application of a rare earth doped potassium fluoride bismuth potassium luminescent nanomaterial. The basic composition of the luminescent nanomaterial is K 0.3 Bi 0.7‑x‑y F 2.4 : xYb, yLn, wherein Ln 3+ is one of Er 3+ , Tm 3+ , Ho 3+ , 0≤x≤0.30, 0 ≤y≤0.05, or K 0.3 Bi 0.7‑z‑t F 2.4 :zM,tN, where M and N are Ce 3+ , Pr 3+ , Nd 3+ , Sm 3+ , Gd 3+ , Eu 3+ , Tb 3+ , one or both of Dy 3+ , 0≤z<0.35, 0≤t<0.35. The preparation method includes the following steps: adding a Bi-containing compound and a rare-earth element-containing compound into a dilute hydrochloric acid solution, stirring and dissolving at room temperature to 90° C. to prepare a solution A; adding potassium fluoride into deionized water, and at room temperature to 90° C. Stir and dissolve at 90°C to prepare solution B; add solution A to solution B and stir at room temperature to 90°C. After the reaction is completed, the obtained precipitate is centrifuged and washed with distilled water. The invention solves the problems in the prior art that the bismuth-containing rare earth-doped light-emitting nanomaterial is synthesized at low temperature and the stability is poor and the bismuth-containing rare-earth-doped light-emitting nanomaterial is rapidly synthesized in an aqueous solution.
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