http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-111961052-B
Outgoing Links
| Predicate | Object |
|---|---|
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02P20-584 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D471-04 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D471-04 |
| filingDate | 2020-09-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 2022-06-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2022-06-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CN-111961052-B |
| titleOfInvention | Preparation method of gamma-carboline derivative |
| abstract | The invention discloses a preparation method of gamma-carboline derivatives and compounds thereof, wherein ketoxime and alkynyl silane compounds are used as raw materials in [ Cp ] * RhCl 2 ] 2 (Pentamethylcyclopentadienyl) rhodium (III) dichloride and AgSbF 6 Under the catalytic condition of (silver hexafluoroantimonate), Trifluoroethanol (TFE) is used as a solvent to react to prepare the gamma-carboline derivative. The invention has the advantages that: the method has the advantages of mild reaction conditions, simple operation, cheap and easily-obtained raw materials, wide substrate application range, excellent yield of most substrates, redox neutral conditions, no harsh reaction conditions such as low temperature or high temperature and the like, and unique reverse regioselectivity induced by steric hindrance. |
| priorityDate | 2020-09-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 84.