http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-111909387-B
Outgoing Links
Predicate | Object |
---|---|
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-1691 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-29 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G83-008 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C47-542 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C47-575 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C47-55 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-29 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C47-546 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C47-54 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G83-00 |
filingDate | 2020-07-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2022-02-22-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2022-02-22-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-111909387-B |
titleOfInvention | Co-based metal organic framework compound and preparation method and application thereof |
abstract | The invention discloses a Co-based metal organic framework compound with a chemical formula of (Me) 2 NH 2 ) 2 [Co 3 (L) 2 (H 2 O) 2 ]2DMF, wherein, the organic linker H 4 L is [3, 5-di (2 ', 4' -dicarboxylic acid) pyridine],L 4‑ Is a deprotonated organic ligand. The crystal structure of the Co-based metal-organic framework compound belongs to a monoclinic system, and the space group is P2 1 And/n. The invention also discloses a preparation method thereof, which comprises the following steps: under a sealing condition, the organic ligand H 4 L、Co(NO 3 ) 2 ·6H 2 O、DMF、CH 3 CN and distilled water are uniformly mixed and react under the solvothermal condition to obtain the Co-based metal organic framework compound. The Co-based metal organic framework compound can be applied to catalyzing the oxidation reaction of benzyl alcohol and derivatives thereof, shows high-efficiency catalysis efficiency, and does not generate byproducts. |
priorityDate | 2020-07-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 35.