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filingDate 2019-04-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2022-04-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2022-04-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-111848928-B
titleOfInvention Conjugated microporous carbazole polymer, preparation method and application thereof, fluorescent film and preparation method thereof
abstract The invention relates to the field of high molecular materials, and provides a conjugated microporous carbazole polymer, a preparation method and application thereof, a fluorescent film and a preparation method thereof. The invention carries out oxidative autopolymerization on 1,3,6, 8-tetra (4- (9H-carbazole-9-yl) phenylpyrene under the induction action of an oxidant to obtain the conjugated microporous carbazole polymer, the polymer has good thermal stability and smaller pore diameter, can show stronger luminescence under the irradiation of ultraviolet light due to the pyrene unit in the structure of the polymer, has extremely high selectivity and sensitivity to PA, can detect PA by a fluorescence quenching method, can make the detection more convenient and easy to implement when being applied to the detection of nitro explosives after being made into a fluorescent film, and has wide application prospect in the fields of photocell, cell imaging, photocatalysis and the like as the conjugated polymer.
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