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publicationDate 2020-10-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-111841640-A
titleOfInvention A kind of cobalt-based organic catalyst and its preparation method and its application of transforming CO2 to synthesize benzazepine heterocycle
abstract The invention relates to the field of catalysts. In view of the problem of insufficient catalytic performance of non-precious metal catalysts, the invention provides a cobalt-based organic catalyst, which has a sea urchin-shaped surface structure formed by a plurality of rod-shaped structures that are distributed from the center to the periphery. Pores with a pore size of 5‑100 nm. The sea urchin-shaped catalyst has the advantages of high specific area, low bulk density and multiple active crystal planes, and the catalyst is a mesoporous material with large specific surface area. The invention also relates to a preparation method of the above cobalt-based organic catalyst, which can prepare a sea urchin-shaped cobalt-based catalyst without a template agent, and realize the control of the product shape. The present invention also provides an application of the above-mentioned cobalt-based organic catalyst to convert CO 2 to synthesize benzazepine heterocycles, adding the cobalt-based organic catalyst and anthranilonitrile compounds into an organic solution, and continuously blowing CO 2 gas, The photocatalytic reaction is carried out under visible light. The reaction conditions are mild.
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