http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-111841537-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_a1f45e4fe7eeb9a68b5ab9e2b0b8de28 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C213-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-1004 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J23-72 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-1028 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-026 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-023 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-0066 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J35-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J35-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C215-28 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J23-72 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C213-00 |
filingDate | 2020-08-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6f6ea86cecd6c27c2f17a0deeaadc60f |
publicationDate | 2020-10-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-111841537-A |
titleOfInvention | 3D (three-dimensional) mesh Cu-based catalyst and preparation method and application thereof |
abstract | The invention discloses a 3D mesh Cu-based catalyst, a preparation method thereof and application thereof in a reaction for preparing chiral amino alcohol by catalyzing hydrogenation of chiral amino acid ester. The catalyst comprises a framework and an active component, wherein the framework is UiO-66, and the active component is Cu. The preparation method comprises the following steps: mixing N, N-dimethylformamide and formic acid, adding ZrOCl 2 And terephthalic acid, performing ultrasonic treatment until the solid is dissolved, and performing hydrothermal reaction, solid-liquid separation, washing and drying on the obtained mixed solution to obtain the UiO-66; mixing the salt solution of Cu with UiO-66 under stirring to obtain a mixtureStanding, aging, drying and roasting to obtain the 3D reticular Cu-based catalyst. The metal Cu in the 3D reticular framework prepared by the method is uniformly dispersed, and the method has the advantages of controllable active component particle size, high amino acid ester conversion rate, good amino alcohol selectivity, good product configuration retention, high optical selectivity and the like. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-112675834-A |
priorityDate | 2020-08-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 52.