http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-111748085-B

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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C251-24
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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G63-42
filingDate 2020-07-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-09-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-09-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-111748085-B
titleOfInvention Biodegradable material multi-block polyester and preparation method thereof
abstract The invention provides a biodegradable material multi-block polyester and a preparation method thereof, wherein the method comprises the following steps: under the action of a catalyst, lactide, phthalic anhydride and cyclohexene oxide are subjected to ring-opening copolymerization reaction in a solvent to obtain multi-block polyester; the catalyst is a Schiff base manganese compound with a structure shown in a formula I. The method provided by the invention adopts the Schiff base manganese compound with the structure of formula I to catalyze the ring-opening copolymerization of lactide, anhydride and cyclohexene oxide, the catalyst has NNOO tridentate coordination capacity, can form a metal active center binding site, is a four-coordination Schiff base manganese catalyst, has good activity for two different types of ring-opening polymerization, has high selectivity for monomers, and can realize adjustable multi-block polymerization reaction. According to the preparation method, 7 sections of polylactide-polyanhydride epoxy copolymer can be obtained through three times of anhydride addition, and the highest molecular weight can reach 47 kg/mol.
priorityDate 2020-07-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 48.