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filingDate 2019-03-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-09-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-09-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-111718383-B
titleOfInvention [Ag(NH3)2]6@Ti4L6Molecular cage crystalline substance and preparation method and application thereof
abstract The invention belongs to the technical field of crystal material preparation, and particularly relates to [ Ag (NH) 3 ) 2 ] 6 @Ti 4 L 6 A molecular cage crystalline substance and a preparation method and application thereof. The inventors successfully designed and synthesized [ Ag (NH) 3 ) 2 ] 6 @Ti 4 L 6 Molecular cage crystalline state. The synthesis process has less pollution and meets the requirement of environmental protection. In addition, [ Ag (NH) ] prepared by the synthesis method 3 ) 2 ] 6 @Ti 4 L 6 The molecular cage crystalline substance has a tetrahedral cage structure, the yield is up to more than 90%, and the product can be used for separating silver from silver ore or recovering silver from silver-containing waste liquid. The method of the invention can convert silver in silver ore or silver-containing waste liquid into [ Ag (NH) 3 ) 2 ] 6 @Ti 4 L 6 Molecular cage crystalline, and can convert [ Ag (NH) 3 ) 2 ] 6 @Ti 4 L 6 The molecular cage crystalline substance is reduced into silver simple substance or silver oxide. Therefore, from the viewpoint of environmental protection, the invention develops an environment-friendly new silver recovery process through environment-friendly chemistry, and provides a feasible method for replacing the leaching of silver by using toxic cyanide salt.
priorityDate 2019-03-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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