http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-111710785-A

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publicationDate 2020-09-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-111710785-A
titleOfInvention A pinhole-free large-area controllable growth perovskite film-forming process
abstract The invention relates to a perovskite film - forming process without pinholes and large-area controllable growth. The isopropanol solution of MAI/FAI was spin-coated on the PbI 2 film. The beneficial effects of the present invention are as follows: the present invention provides a low-surface-energy material for large-area thermal evaporation and film quality improvement, which reduces the nucleation activation energy and enhances the deposition of the PbI 2 layer; The reaction is completely carried out, and the rough surface of the bottom layer is better covered. The use of low surface energy additives better matches the polarity of the substrate and the perovskite layer, which effectively avoids the phenomenon of shrinkage caused by the change of local hydrophilicity and hydrophobicity. At the same time as the film quality, the crystal quality can be effectively controlled to achieve a controllable large-area dense and pinhole-free film formation technology.
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