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filingDate 2020-04-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-10-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-10-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-111411368-B
titleOfInvention Method for treating dichloromethane through electrochemical dechlorination under catalysis of palladium
abstract The invention discloses a method for treating dichloromethane by electrochemical dechlorination under the catalysis of palladium. The method takes an acidic solution as a reaction medium, and dichloromethane is added into the acidic solution to form an electrolytic reaction liquid as a catholyte; taking an alkaline aqueous solution as an anolyte; adding activated carbon-supported cubic palladium nanoparticles serving as a cathode catalyst into catholyte; the foamed glassy carbon is taken as a cathode current collector, and a chemically inert conductive material or a titanium metal coated with noble metal oxide in an anolyte is taken as an anode and is placed in an electrolytic bath for electrochemical reaction. Wherein the pH of the catholyte is kept between 1 and 5 in the reaction process. The invention realizes the conversion of dichloromethane into methane with high selectivity (more than or equal to 90 percent) by an electrochemical method, and is favorable for recovery. According to the invention, the activated carbon loaded cubic palladium nanoparticles are used as the catalyst, and the catalytic activity of the electrolytic reaction solution can be obviously improved in a specific system of the invention.
priorityDate 2020-04-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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