http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-111313042-B
Outgoing Links
Predicate | Object |
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classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02E60-50 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B82Y30-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/H01M4-9016 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/H01M4-9083 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/H01M8-1011 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B82Y30-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/H01M4-90 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/H01M8-1011 |
filingDate | 2019-11-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2021-11-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2021-11-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-111313042-B |
titleOfInvention | Double-functional oxidation electrocatalyst and preparation method thereof |
abstract | The invention provides a preparation method of a bifunctional oxidation electrocatalyst, which is a graphene-like carbon nanosheet bifunctional catalyst prepared by controllably synthesizing cobalt-nickel bimetallic oxide nanoparticles coated with carbon shells by a simple one-step pyrolysis method. The graphene-like sheet nano layer and the graphitized carbon shell provide an electron transmission channel for the cobalt-nickel oxide nano particles, and the electron transmission resistance in the reaction process is reduced. Mesopores (about 3nm) distributed on the three-dimensional graphene-like nanosheets and the carbon shell provide channels for material exchange between the electrolyte solution and the nanoparticles, and the material transport capability of the cobalt-nickel oxide is enhanced. The graphite carbon shell reduces the Oswald ripening effect, and makes the cobalt nickel oxide more stable in the dual-function catalysis. The synergistic effect of the cobalt nickel oxide nanoparticles with the diameter of 30-50nm and the nitrogen-doped graphitized carbon shell which are uniformly distributed on the surface of the sheet layer brings about more excellent oxygen reduction activity (the half-slope potential is 0.78V), oxygen evolution reaction activity (the initial potential is 1.26V) and methanol tolerance than 20% of Pt/C. |
priorityDate | 2019-11-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 44.