http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-111303388-B

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filingDate 2020-03-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-08-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-08-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-111303388-B
titleOfInvention Preparation method of hydrolysis-resistant PBT polyester resin
abstract The invention relates to a method for preparing hydrolysis-resistant PBT polyester resin, which comprises the steps of mixing terephthalic acid, 1, 4-butanediol, organic titanate compound and magnesium phosphate to prepare slurry, carrying out esterification reaction to obtain prepolymer, carrying out melt polycondensation reaction to obtain a PBT polyester resin substrate, and finally mixing the PBT polyester resin substrate, a terminal capping modifier and an organic phosphate compound in a double-screw extruder to obtain the hydrolysis-resistant PBT polyester resin; according to the mass fraction, the required addition proportion of each substance in the mixing preparation process is as follows: 97-99 parts of a PBT polyester resin substrate, 0.5-1 part of a terminal-capping modifier and 0.01-1 part of an organic phosphate compound; the end-capping modifier is hyperbranched polyester with 6-100 hydroxyl groups at the end and 2, 2-dimethylolpropionic acid as a branching unit. The preparation method is simple, and the prepared hydrolysis-resistant PBT polyester resin has excellent comprehensive performance.
priorityDate 2020-03-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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