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filingDate 2020-03-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2023-01-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2023-01-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-111285983-B
titleOfInvention High/low activity monomer block copolymer and preparation method thereof
abstract The invention relates to a high/low activity monomer block copolymer and a preparation method thereof. The preparation method comprises the following steps: under a protective atmosphere, the high activity monomer, a regulating agent and a thermal initiator are subjected to a polymerization reaction, and the reaction is complete Obtain high activity monomer polymer after the end; Wherein, high activity monomer comprises acrylate monomer or styrene monomer; Regulating agent is xanthate RAFT reagent; Under protective atmosphere, polymerize with high activity monomer The compound is a macromolecular RAFT reagent, which is polymerized with a low-reactivity monomer and a thermal initiator, and the high/low-reactivity monomer block copolymer is obtained after the reaction is complete; wherein, the low-reactivity monomer is a non-conjugated structure Vinyl monomers. The present invention realizes the synthesis of high/low activity monomer block copolymers with controllable molecular weight and molecular weight distribution. The bulk copolymer segment is very pure.
priorityDate 2020-03-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 50.