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filingDate 2019-12-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2022-03-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2022-03-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-111153836-B
titleOfInvention Preparation and application of potassium decafluoro-4- (pentafluoroethyl) cyclohexyl-1-sulfonate
abstract The invention relates to preparation and application of potassium decafluoro-4- (pentafluoroethyl) cyclohexyl-1-sulfonate, and belongs to the technical field of fine fluorine chemical industry. According to the method, p-ethyl benzene sulfonyl chloride is used as a raw material, is firstly converted into p-ethyl benzene sulfonyl fluoride, and then is subjected to electrolytic fluorination in the presence of n-butyl mercaptan, the electrolytic yield is over 50 percent, the decafluoro-4- (pentafluoroethyl) cyclohexyl-1-sulfonyl fluoride obtained through electrolysis is rectified and then is hydrolyzed with KOH aqueous solution to obtain potassium decafluoro-4- (pentafluoroethyl) cyclohexyl-1-sulfonate with the purity of more than 98 percent, and the prepared potassium decafluoro-4- (pentafluoroethyl) cyclohexyl-1-sulfonate has a good application prospect in aviation hydraulic oil.
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