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filingDate 2019-12-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-04-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-04-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-111040225-B
titleOfInvention Repeatedly erasable anti-counterfeiting film based on photonic crystal structural color and preparation method and application thereof
abstract The invention discloses a rewritable anti-counterfeiting film based on photonic crystal structural color and a preparation method and application thereof. Soaking a photonic crystal film of cellulose nanocrystals in a mixed solution of ionic liquid methacryloyloxyethyl trimethyl ammonium chloride, a cross-linking agent, an initiator and absolute ethyl alcohol, performing illumination polymerization, covering the anti-counterfeiting film with a hollow patterned polyester film, and dropwise adding a solution containing ClO 4 ‑ 、Tf 2 N ‑ Or PF 6 ‑ At least one kind of hydrophobic anion solution to obtain a structural color anti-counterfeiting film loaded with a hidden pattern in a natural state, and the structural color anti-counterfeiting film responds to complete corresponding pattern information under the condition of water jet excitation; the anti-counterfeiting film is soaked in a soluble chloride solution, and then the hidden pattern can be wiped off. The invention utilizes the interchange of hydrophobic ions and hydrophilic ions to prepare the anti-counterfeiting film which has high sensitivity, reversible erasing and writing and showing and hiding functions and certain mechanical strength, and realizes the wiping and recoding of information.
priorityDate 2019-12-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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