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publicationDate 2020-03-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-110890548-A
titleOfInvention A kind of preparation method and application of pitch coke activated carbon supported cobalt phthalocyanine catalytic material
abstract A preparation method and application of a pitch coke activated carbon supported cobalt phthalocyanine catalytic material. The phthalic anhydride and the pretreated pitch coke activated carbon are mixed uniformly, and then urea, ammonium molybdate and cobalt salt are added, and sintered to obtain Pitch coke activated carbon supported cobalt phthalocyanine catalytic material. The method has the advantages of simple preparation process, low cost, short synthesis period, uniform composition and the like. The prepared catalytic material has a porous skeleton structure, which is beneficial to the rapid penetration and electron transport of the electrolyte. The high specific surface area, abundant pore structure and surface carboxylated functional groups of pitch coke activated carbon are favorable for combining with cobalt phthalocyanine in the form of hydrogen bonds or covalent bonds, which can stabilize the structure of the catalytic material and improve the conductivity. Using the synergistic and competitive effect of the two to improve the catalytic performance of the material and accelerate the reduction of thionyl chloride, a sparse LiCl film is formed during the discharge process, reducing the internal resistance of the battery, and finally effectively improving the electrochemical performance of lithium thionyl chloride batteries.
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Total number of triples: 52.