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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F2-48
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F120-14
filingDate 2019-12-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-09-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-09-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-110885388-B
titleOfInvention Application of binaphthol derivative in active free radical photopolymerization
abstract The application of the binaphthol derivative in the aspect of active free radical photopolymerization reaction. The invention relates to the field of organic photocatalyst catalytic controllable active radical polymerization, in particular to an organic catalytic system in which 1,1 '-bi-2, 2' -naphthol derivatives are used as an organic photocatalyst and active controllable radical photopolymerization is carried out under visible light. The BINOL polymer is used as an organic light oxidation-reduction catalyst, so that the rapid reversible balance between a dormant species and an active chain can be realized, the polymerization reaction has controllability, and a brand new application method on organic light catalytic activity free radical polymerization is provided for the BINOL organic polymer while the homopolymer and the block copolymer with controllable molecular weight and low polydispersity can be prepared; the organic photocatalytic system has the advantages of high efficiency, low cost and easy operation, and the prepared polymer has the characteristics of controllable molecular weight and narrow polydispersity and conforms to the production concept of environment-friendly green production.
priorityDate 2019-11-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 51.