http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-110776593-A

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filingDate 2019-11-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9d0fadbeff3a1ea3eb9583b01590ca97
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publicationDate 2020-02-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-110776593-A
titleOfInvention Visible light response azobenzene macromolecular copolymer and synthesis method and application thereof
abstract The invention discloses a visible-light-responsive azobenzene macromolecular copolymer, and a synthesis method and application thereof, and belongs to the technical field of new material synthesis. The method comprises the following steps: acryloyl chloride, m-methyl red, N-hydroxysuccinimide, ethylenediamine, hydroxyethyl methacrylate, N-vinyl pyrrolidone, an anhydrous nonpolar oil phase solvent, a polymerization solvent, ethyl acetate and nitrogen. According to the invention, a macromolecular optical switch with rapid visible light response and controllable recovery is obtained by copolymerizing an azobenzene monomer with para-position substitution with free radicals of hydrophobic monomers and hydrophilic monomers in different proportions; the introduction of the specific functionalized monomer enables the azobenzene molecule to have the characteristic of functionalization, and overcomes the defects that the azobenzene molecule in the prior art can only realize reversible forward and reverse transformation under the action of ultraviolet light, and the transformation is irreversibly attenuated after being circulated for several times.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-114561028-A
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