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filingDate 2019-09-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2020-01-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-110684041-A
titleOfInvention Subnaphthalocyanine acceptor material and its synthesis method and solar cell
abstract The sub-naphthalocyanine acceptor material, a synthesis method and a solar cell of the invention belong to the technical fields of organic synthesis and optoelectronics. Using 6,7-dicyanonaphthalene monoimide compound and boron trichloride as raw materials, in an organic solvent, the reaction is stirred at a certain temperature to generate chloronaphthalene phthalocyanine triimide. Naphthalocyanine triimide undergoes fluorine substitution, phenoxy substitution or phenylthio substitution, and finally a series of naphthalocyanine molecular acceptor materials are obtained. In the invention, imide groups are designed to be introduced into unsubstituted naphthalene phthalocyanine molecules, and a new type of acceptor material with good solubility, simple separation and purification and suitable LUMO energy level is synthesized. This type of acceptor material has a photoelectric conversion efficiency of up to 6.25% in bulk heterojunction solar cells with simple device structure requirements, and is a solution-processable organic solar energy of subphthalocyanine, subnaphthalocyanine, phthalocyanine and naphthalocyanine. The highest photoelectric conversion efficiency in the battery.
priorityDate 2019-09-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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