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publicationDate 2020-01-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-110652993-A
titleOfInvention Study on the performance of a cobalt azagraphene-based catalyst for hydrogen production from ammonia borane
abstract The invention discloses a study on the performance of a cobalt azagraphene-based catalyst for catalyzing ammonia borane to produce hydrogen. In addition to being used as a high-energy hydrogen storage material, ammonia borane and its derivatives can also be used as reducing agents in the field of organic synthetic chemistry in recent years for the reduction of aldehydes, ketones and carbonyl compounds. Compared with traditional reducing agents, ammonia borane has The reaction conditions are mild, the selectivity is strong, and the product yield is high. Ammonia borane compound (NH 3 BH 3 ) is a new chemical hydride hydrogen storage material that has recently received close attention. It has the advantages of ultra-high hydrogen density (19.6wt%), good thermal and chemical stability, and with broadly application foreground. Among them, the hydrogen production rate of ammonia borane is the fastest under T=298K and 15% NaOH, the TOF value is 54moL H2.min - 1.moL Ca -1 , and the apparent activation energy is 27.1kJ/mol, wherein the loading of metallic cobalt The successful preparation of this catalyst is of great significance for hydrogen production from ammonia borane.
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