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filingDate 2019-10-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2022-04-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2022-04-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-110615488-B
titleOfInvention V-doped NiO-coated V-doped Ni3S2Preparation method of core-shell structure
abstract V-doped NiO coatedV doping with Ni 3 S 2 A preparation method of a core-shell structure. Adding vanadium chloride and urea into ultrapure water to obtain a solution A; placing the solution A and the foamed nickel in a reaction liner and sealing, then placing the reaction liner in a homogeneous phase reactor for hydrothermal reaction, and then cleaning and drying to obtain NiV-LDH/NF growing on the foamed nickel in situ; putting the thioacetamide solution NiV-LDH/NF into a hydrothermal kettle for hydrothermal reaction, and cooling to room temperature; placing the reaction kettle at room temperature for 20-24h, taking out the foamed nickel, cleaning and drying to obtain V-doped Ni coated with V-doped NiO 3 S 2 An electrocatalytic material with a core-shell structure. According to the method, foam nickel is used as a nickel source, vanadium chloride and urea are respectively used as a vanadium source and an alkali source, a NiV-LDH/NF precursor growing on the surface of the foam nickel in situ is obtained, the release of nickel ions in the foam nickel is accelerated and the morphology of the NiV-LDH is regulated and controlled due to the existence of vanadium ions, and the obtained in-situ NiV-LDH/NF has extremely high structural stability. The prepared composite material with the final core-shell structure has excellent electrocatalytic oxygen and hydrogen evolution performance and stability, and fast reaction kinetics.
priorityDate 2019-10-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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