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filingDate 2019-09-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2022-07-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2022-07-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-110607046-B
titleOfInvention Flame-retardant polyvinyl alcohol aerogel and preparation method thereof
abstract The invention discloses a flame-retardant polyvinyl alcohol aerogel which is prepared by carrying out a cross-linking reaction on polyvinyl alcohol and phosphorylated cellulose. The preparation method comprises the following steps: s1, adding cellulose and phosphorous acid into molten urea, reacting for 4-8h at 140-180 ℃, adding water and ethanol, and separating out precipitate to obtain phosphorized cellulose; s2, ultrasonically dispersing the phosphated cellulose in water; s3, dissolving polyvinyl alcohol in water at 80-95 ℃; s4, adding a phosphorized cellulose solution into a polyvinyl alcohol aqueous solution, then adding a cross-linking agent aqueous solution, and reacting at the temperature of 60-85 ℃ for 1-4 h to prepare a polyvinyl alcohol/phosphorized cellulose cross-linked hydrogel; s5, freeze-drying the hydrogel for 24-72 hours to obtain the flame-retardant polyvinyl alcohol aerogel. The polyvinyl alcohol aerogel disclosed by the invention has excellent flame retardant property and excellent mechanical property because the phosphorized cellulose contains a large amount of P elements.
priorityDate 2019-09-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 48.