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filingDate 2019-08-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9145c40eba27a6444da5ff81e2ae6b24
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publicationDate 2019-12-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-110527105-A
titleOfInvention A kind of ultra-thin two-dimensional porous metal-organic framework nanosheet and its preparation method
abstract The invention discloses an ultra-thin two-dimensional porous metal-organic framework nanosheet and a preparation method thereof, belonging to the field of new materials, adopting a method of coordination substitution, and replacing the original ligand in the metal-organic framework nanosheet by dimethylimidazole The benzimidazole reduces the interlayer conjugation and realizes the peeling effect, and the method has the advantages of high yield and low cost. In the present invention, benzimidazole and zinc nitrate hexahydrate are used as ligands and metal coordination centers of MOF, and 2-methylimidazole is used as a replacement ligand of MOF; two-dimensional MOF nanosheets are synthesized by using solvothermal technology and suction filtration technology; Freeze-drying technology is used to form a porous structure on the obtained two-dimensional MOF nanosheets; the ratio of 2-methylimidazole to benzimidazole is controlled to obtain ultrathin two-dimensional porous MOF nanosheets.
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priorityDate 2019-08-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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