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filingDate 2019-07-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-07-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-07-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-110467214-B
titleOfInvention Samarium oxychloride nanosheet and preparation method and application thereof
abstract The invention discloses a samarium oxychloride nanosheet and a preparation method and application thereof, wherein the samarium oxychloride nanosheet is in an amorphous smoke two-dimensional samarium oxychloride nanosheet structure, and the preparation process comprises the following steps: (1) mixing trihydroxymethyl aminomethane and hydrochloric acid to obtain a buffer solution, adding a soluble samarium source and graphene oxide, performing ultrasonic treatment to obtain a uniformly dispersed suspension, performing solid-liquid separation after reaction, and drying to obtain a precursor; (2) the precursor is burned at the temperature of 500-600 ℃ to obtain the samarium oxide nanosheet. The amorphous smog-shaped two-dimensional samarium oxychloride nanosheet is used as photocatalytic N 2 And H 2 When synthesizing ammonia by O reaction, NH is reacted at room temperature without adding any sacrificial agent 3 The yield reaches 426 mu mol g cat. –1 ·h –1 To reasonably design the photocatalytic N under ambient conditions 2 The fixed high-efficiency catalyst improves a new idea.
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