http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-110465328-B
Outgoing Links
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classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2229-186 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2229-183 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2601-20 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2601-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02P20-10 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-0208 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-0271 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-0205 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C249-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-0033 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J29-89 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C249-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C251-44 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C249-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J29-89 |
filingDate | 2018-05-09-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2022-07-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2022-07-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-110465328-B |
titleOfInvention | The oximation method of ketones |
abstract | The invention discloses a method for oximation of ketones. In order to improve the reaction efficiency and selectivity of oximation, compared with the traditional amidoximation process, the invention firstly adopts a reactive distillation process, and in the presence of a novel magnetically loaded modified titanium-silicon molecular sieve Under the following conditions, hydrogen peroxide and ammonia react to generate hydroxylamine, which is concentrated by rectification to obtain a higher concentration of hydroxylamine aqueous solution, which undergoes oximation reaction with ketone to obtain ketoxime. Under the process conditions, the ketone and hydroxylamine adopt a continuous oximation process, and because the concentration of hydroxylamine is increased, the efficiency is significantly improved, and the removal of ammonia also makes the ketoxime selectivity as high as 99.8%. |
priorityDate | 2018-05-09-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 134.