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filingDate 2019-08-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-04-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-04-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-110407179-B
titleOfInvention Method for synchronously solidifying and stabilizing arsenic sulfide slag and recycling sulfur resources
abstract Synchronization is disclosed hereinA method for solidifying and stabilizing arsenic sulfide slag and recovering sulfur resources mainly adopts a hydrothermal method, arsenic slag is quickly converted into arsenic sodium alunite by introducing a mineralizer aluminum sulfate, conversion conditions are optimized, and the long-term stability of the arsenic sodium alunite is evaluated. Nammite is an extremely stable mineral with a general chemical formula of NaAl 3 (SO 4 ) 2 (OH) 6 Using arsenate (AsO) 4 3‑ ) With sulfate radicals (SO) in the structure of sodalite 4 2‑ ) Substitution of the same similarities between them to form arsenic sodium alunite solid solution (NaAl) 3 (SO 4 ) 2‑x (AsO 4 ) x (OH) 6 ) Thereby realizing the solidification and stabilization of the arsenic. The experimental result shows that x in the arsenic sodium alunite solid solution can reach 0.154, the mass fraction of arsenic is 2.85 percent, and the volume reduction of waste residue is more than 60 percent; the recovery rate of sulfur reaches more than 90%, and the purity of sulfur exceeds 95%. The arsenic leaching toxicity of the arsenic sodium alunite solid solution is evaluated, and the result shows that the leaching concentration of arsenic is 0.1-0.5 mg/L, the requirement of dangerous waste stockpiling is met, and the technology is economical and effective in stabilizing arsenic slag.
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