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filingDate 2018-04-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-08-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-08-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-110387001-B
titleOfInvention A kind of porphyrinated polystyrene elastomer and its preparation method and use
abstract The invention discloses a porphyrinated polystyrene elastomer and a preparation method and application thereof. The porphyrinated polystyrene elastomer is an organic photoelectric conversion material, and the preparation method is as follows: (1) Chloromethylation: the polystyrene elastomer, the chloromethylation reagent and the catalyst are sequentially dissolved in chloroform, and the reaction Completely obtain chloromethylated polystyrene elastomer; (2) Aldehydization: Dissolve chloromethylated polystyrene elastomer, dimethyl sulfoxide, potassium iodide and sodium bicarbonate in xylene in turn (3) Porphyrinization: Dissolve the formaldehyde polystyrene elastomer, substituted or unsubstituted benzaldehyde, pyrrole, and lactic acid in xylene in turn , the reaction is complete and the porphyrinated polystyrene elastomer is obtained. When the porphyrin grafting ratio of the organic photoelectric conversion material is within the specific range of 5% to 55% of the present invention, the organic photoelectric conversion material has excellent photoelectric responsiveness while maintaining its elasticity and flexibility.
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