http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-110294771-B
Outgoing Links
Predicate | Object |
---|---|
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B2200-13 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F5-003 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/H01F1-42 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/H01F1-42 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F5-00 |
filingDate | 2019-07-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2022-03-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2022-03-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-110294771-B |
titleOfInvention | Six-nuclear dysprosium cluster annular complex monomolecular magnet and preparation method thereof |
abstract | A six-nuclear dysprosium cluster ring complex monomolecular magnet and a preparation method thereof relate to a monomolecular magnet and a preparation method thereof. The purpose of the invention isThe method aims to solve the problems of complex synthesis method, low controllability and poor repeatability of the rare earth complex monomolecular magnet prepared by the existing method. The chemical formula of the hexanuclear dysprosium cluster annular complex monomolecular magnet is [ Dy 6 (H 2 shi) 6 (2‑pyca) 6 (2‑pyca ‑ ) 6 ]Molecular formula is C 114 H 90 Dy 6 N 18 O 42 . The method comprises the following steps: salicylhydroxamic acid, pyridine-2-formic acid and Dy (NO) 3 ) 3 ·6H 2 Dissolving O in a solvent, performing ultrasonic treatment to obtain a mixed solution, heating and refluxing the mixed solution, and adding pyridine to obtain a preform; and (4) volatilizing the solvent for the preform to obtain the hexanuclear dysprosium cluster annular complex monomolecular magnet. The invention can obtain the hexanuclear dysprosium cluster ring complex monomolecular magnet. |
priorityDate | 2019-07-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 31.