http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-110294689-B
Outgoing Links
| Predicate | Object |
|---|---|
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-821 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-76 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-2295 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C253-00 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C253-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C255-50 |
| filingDate | 2019-06-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 2021-04-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2021-04-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CN-110294689-B |
| titleOfInvention | Method for preparing nitrile compound by dehydrogenation of primary amine under catalysis of ruthenium metal complex |
| abstract | The invention provides a method for preparing nitrile compounds by dehydrogenation of primary amine under the catalysis of ruthenium metal complexes, belonging to the technical field of energy and homogeneous catalysis. The invention successfully designs and synthesizes a series of ruthenium metal complex catalysts, and can efficiently catalyze the dehydrogenation of primary amine compounds to prepare nitrile compounds. The invention has the advantages of simple preparation method, good stability, high selectivity and wide substrate applicability. Taking the example of preparing nitrile by dehydrogenating benzylamine, the yield of benzonitrile can reach 95 percent. The reaction does not need to use a high-toxicity cyanation reagent and a strong oxidant, thereby avoiding the pollution to the environment and eliminating the potential safety hazard. The only byproduct of the catalytic reaction is hydrogen, which can be used as both a green energy source and a hydrogen source for other reactions. In addition, the realization of the catalytic reaction also provides a thought for the amine substance as the liquid hydrogen storage material. |
| priorityDate | 2019-06-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 59.