| Predicate |
Object |
| assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_74ca034abd5ce84d1c39ff9a5b6f915f |
| classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2601-20
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B2200-05
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2527-057 |
| classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B59-001
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C41-24
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C15-18
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C1-26
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C1-30
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F8-04
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C37-002 |
| classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F114-06
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C15-18
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C43-205
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C1-30
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C1-26
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B59-00
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C37-00
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F8-04
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C15-04
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C39-16
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C41-24
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C13-277 |
| filingDate |
2019-05-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_26cb1a5b099f525870b4e42e7cd080da
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_c3150e1e07344d9312c258a05a4ec88a
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1d7756991db8287a25c02df1686457b5
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_14c76626a3b1b224e9cfa89cac68505e
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a68e2533cc5c81095a15e0b9a31cabab |
| publicationDate |
2019-09-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber |
CN-110204425-A |
| titleOfInvention |
A kind of conversion method of carbon-halogen bond C-R of photocatalytic polyhalide to carbon-hydrogen/deuterium bond C-H/D |
| abstract |
The invention discloses a method for converting carbon-halogen bonds C-R of photocatalytic polyhalogens to carbon-hydrogen/deuterium bonds C-H/D, comprising the following steps: adding photocatalyst quantum dots/rods into a solvent to obtain solution A ; Add polyhalide and electron sacrificial body to solution A to obtain solution B; irradiate solution B with a light source to catalyze the dehalogenation of polyhalide. The invention is the first time that nano quantum dots and nano quantum rods are used in the dehalogenation conversion reaction of polyhalogenated compounds. The reaction conditions are mild, the visible light is used as the driving energy, and the product is a completely dehalogenated hydrocarbon compound. The whole process is green, concise and efficient. . In the invention, the dehalogenation conversion and deuterium labeling process of polyhalides are combined to complete the conversion of multiple C-R bonds to C-D bonds, and the deuterium labeling of polyatoms is realized in one step. |
| isCitedBy |
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-111592442-B
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-111644131-A
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-114054046-A
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-111592442-A |
| priorityDate |
2019-05-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type |
http://data.epo.org/linked-data/def/patent/Publication |