http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-110156581-B
Outgoing Links
Predicate | Object |
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classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-512 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C47-575 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C281-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D229-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C47-54 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D273-04 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-51 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D273-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D229-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C281-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C47-575 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C47-54 |
filingDate | 2019-06-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2021-07-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2021-07-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-110156581-B |
titleOfInvention | Method for one-step photocatalytic lignin depolymerization and amine synthesis into nitrogen-containing aromatic compound |
abstract | A method for one-step photocatalytic lignin depolymerization and amine synthesis into a nitrogenous aromatic compound belongs to the technical field of lignin application. Dissolving lignin or a model compound thereof serving as a reaction substrate in a solvent, reacting for 6-24 hours at room temperature under the assistance of an auxiliary agent and a nitrogen source under the excitation of a light source and the catalysis of a photocatalyst, and carrying out selective cracking and amination on a C-C bond so as to synthesize a nitrogen-containing aromatic compound; the molar ratio of lignin or a model compound thereof, the photocatalyst, the auxiliary agent and the nitrogen source is 100: (1-20): (1-100): 100. the method has the advantages of simple reaction steps, mild reaction conditions, high bond breaking selectivity, high product selectivity, 100% atomic efficiency, environmental protection, realization of selective cracking and amination of C-C bonds through one-step reaction, continuous feeding, good degradation effect on natural lignin, capability of obtaining nitrogen heterocyclic compounds through further reaction of hydrazine products and the like. |
priorityDate | 2019-06-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 109.