http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-110105169-B
Outgoing Links
Predicate | Object |
---|---|
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-34 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-49 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-845 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02P20-52 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-0252 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-004 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C67-37 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-20 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-2243 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-2217 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-1805 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C29-149 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C29-154 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-675 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-154 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C31-20 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-37 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22 |
filingDate | 2019-06-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2020-10-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2020-10-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-110105169-B |
titleOfInvention | Method for preparing 1, 3-propylene glycol by coupling ethylene oxide with synthesis gas |
abstract | A method for preparing 1, 3-propylene glycol by coupling ethylene oxide with synthesis gas relates to the field of preparing 1, 3-propylene glycol, and comprises the steps of preparing 3-hydroxypropionate by performing ring-opening-carbonylation-esterification catalytic reaction on ethylene oxide, carbon monoxide and alcohol molecules, and preparing 1, 3-propylene glycol by performing hydrogenation catalytic reaction on the 3-hydroxypropionate. The catalytic reaction of ethylene oxide, carbon monoxide and alcohol is realized by using a metal complex catalyst coordinated by N, O-ligand under the action of an organic solvent and an auxiliary agent, and the yield of 3-hydroxypropionate can reach 97%. The catalytic reaction of 3-hydroxy propionate and hydrogen is carried out by using copper-containing mixed metal silicon oxygen catalyst, and the yield of 1, 3-propylene glycol can reach 73%. The alcohol generated in the second step hydrogenation catalytic reaction can be recycled for the first step ring-opening-carbonylation-esterification catalytic reaction. |
priorityDate | 2019-06-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 206.